2-[4-(Methylsulfanyl)phenyl]naphtho[1,8-de][1,3,2]diazaborinane
نویسندگان
چکیده
The title compound, C(17)H(15)BN(2)S, is one member in a series of diaza-borinanes featuring substitution at the 1-, 2- and 3-positions in the nitro-gen-boron heterocycle. The dihedral angle between the mean planes of the naphthalene and phenyl ring systems is 19.86 (6)°. In the crystal structure, two C-H⋯π inter-actions link the mol-ecules into sheets which lie parallel to the bc plane. There is a π-π inter-action between each pair of centrosymmetrically related sheets [centroid-centroid distance = 3.5922 (8) Å].
منابع مشابه
2-(4-Chlorophenyl)naphtho[1,8-de][1,3,2]diazaborinane
The title compound, C(16)H(12)BClN(2), is one in a series of diaza-borinanes, derived from 1,8-diaminona-phthalene, featuring substitution at the 1, 2 and 3 positions in the nitro-gen-boron heterocycle. The structure deviates from planarity, the torsion angle subtended by the p-chloro-phenyl ring relative to the nitro-gen-boron heterocycle being -44-.3(3)°. The mol-ecules form infinite chains w...
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The title compound, C(16)H(13)BN(2), is one compound in a series of diaza-borinanes featuring substitution at the 1, 2 and 3 positions in the nitro-gen-boron heterocycle. The title compound is slightly distorted from planarity, with a dihedral angle of 9.0 (5)° between the mean planes of the naphthalene system and the benzene ring. The m-carbon atom of the benzene ring exhibits the greatest dev...
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متن کاملSynthesis, structure and metal ion binding of di-(1,8-naphtho)-16-crown-4 compounds
The syntheses of two di(1,8-naphtho)-16-crown-4 compounds are described. In the X-ray structure of di(1,8-naphtho)-16-crown-4, the compound crystallizes in the orthorhombic space group Pna21 with four molecules per asymmetric unit. Alkali metal cation selectivities of the ionophores are assessed in solvent polymeric membrane electrodes.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011